N,N′-Bis[(E)-(2-chloro-8-methylquinolin-3-yl)methylidene]ethane-1,2-diamine

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N,N′-Bis[(E)-(2-chloro-8-methyl­quinolin-3-yl)methyl­idene]ethane-1,2-diamine

The complete mol-ecule of the title compound, C(24)H(20)Cl(2)N(4), is generated by a crystallographic inversion centre. A kink in the mol-ecule is evident [C-N-C-C torsion angle = -147.0 (3)°] owing to the twist in the central ethyl-ene bridge. Further, there is a small twist between the imine [N=C = 1.267 (3) Å] and quinoline residues [N-C-C-C = -12.4 (4)°]. In the crystal, a combination of π-...

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The mol-ecule of the title centrosymmetric Schiff base compound, C(16)H(12)Cl(2)F(2)N(2), adopts an E configuration with respect to the azomethine C=N bond. The imino groups are coplanar with the aromatic rings. Within the mol-ecule, the planar units are parallel, but extend in opposite directions from the dimethyl-ene bridge. An inter-esting feature of the crystal structure is the short inter-...

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2-Chloro-8-methoxy­quinoline-3-carbaldehyde

In the title compound, C(11)H(8)ClNO(2), the quinoline fused-ring system is almost planar (r.m.s. deviation = 0.020 Å). The formyl group is slightly bent out of the quinoline plane [deviation of the O atom = 0.371 (2) Å].

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2-Chloro-8-methyl­quinoline-3-carbaldehyde

The quinoline fused-ring system of the title compound, C(11)H(8)ClNO, is planar (r.m.s. deviation = 0.005 Å); the formyl group is slightly bent out of the plane [C-C-C-O1 torsion angles = 8.8 (7) and -172.8 (4)°].

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(2-Chloro-8-methyl­quinolin-3-yl)methanol

The mol-ecule of title compound, C(11)H(10)ClNO, is close to being planar (r.m.s deviation for the non-H atoms = 0.017 Å). In the crystal, mol-ecules inter-act by way of O-H⋯O hydrogen bonds, generating C(2) chains propagating in [010]. The crystal structure is consolidated by C-H⋯π inter-actions and aromatic π-π stacking inter-actions [centroid-centroid distance = 3.661 (2) Å].

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s160053681004540x